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Web Coating

Blogmaster: Dr. Edward D. Cohen

02

Curl is the tendency of a coated film to curve towards the coated side of the film instead of lying flat can be created in several different parts of the web coating process, substrate manufacture, drying in coating line, lamination, storage and normal usage. Curl is caused in the dryer by  residual stresses in the coating applying a force to the substrate, which causes the substrate to bend. These stresses are affected by the shrinkage of the coating during drying and are increased by rapid drying, and low solvent concentration in the dryer air. The magnitude of these stresses will depend on the drying conditions, amount of shrinkage from the initial wet thickness, the properties of the binder system, the transition temperatures and stress relieving in the dryer

Depending on its severity, curl  can have a detrimental effect during the drying process and if not reduced will effect the functionality of the product when used by the customer. In the dryer the drying generated forces substrate edge to curl and can result in the wet coating contacting the dryer nozzles and causing defect in the coated layer. Figure 1 shows the curl and the initiating stresses.  Curl can be a major problem in a floater dryer because of the close distance, 0 " to 1" between nozzle and web. This is dependent on web type,  web tension, and nozzle design,  between substrate and floater dryer nozzles. Gelatin containing coatings are particularly susceptible to curl and will exhibit severe curl at low relative humidity in the dryer. Also, finished product can curl if stresses are not relieved after exiting the dryer

There are several basic actions that can be taken to reduce dryer curl; Insure substrate has  no inherent curl from manufacturing process, reduce stresses induced by the drying conditions and modify  the product structure to generate less force and make the substrate more resistant to deformation.   

The shrinkage forces in the dryer can be reduced by several actions.  Decreasing the drying rate by lowering temperature and increasing drying air solvent content. This will give more time for the coating to reduce stresses. Increasing the solvent concentration the falling rate zone drying zone will prevent the surface layer from prematurely drying. It will reduce shrinkage stress in  the drying coating, thereby reducing curl. Increasing the relative humidity in space between the end of the dryer and the rewind can plasticize binders that are moisture sensitive reducing stress. Keep the dry point close to the end of the dryer and do not over dry. Reduce the solids concentration to slow down drying and generate less forces.

 

Comments

#304 Jerry Warre
Thursday, January 12, 2012 12:19 PM
Good article. We have tried these techniques. They are effective in varying degrees. However, if the substrate being coated is paper based, adding 10 pound steam to the back side of the web is very effective, even with solvent coatings.
#305 Dhananjay Nachare
Sunday, January 15, 2012 5:12 AM
Dear Edward,

Laminate can't be a curl free. But many times it is visible towards the laminating substrare PE (in pet /Pe structure). I want to know how we can reduce the curling towards the PE. Secondly i had seen that curling sides are different in different atmoshperic condition. Like in hot condition it is showing towards pet or flat and same laminate is showing curling towards pe in below 25 deg C.
How i can stop this phenomena? Is there need to change the PE receipe?

Wednesday, January 18, 2012 2:32 PM
Dear Edward,

I hope you are fine and doing well. We are a flexible Packaging company in Pakistan and operate with solvent less and solvent based lamination. We are recently facing low bond strength (35 ~ 40 g/cm) issues with Bostik solvent free adhesive 515/730 (Mixing Ratio 100:60 ) Adhesive system (the same is observed with the trial samples of Mor-free sent by you to us). The mode or failure is complete ink transfer from base substrate. Our routine understanding is that in such cases where ink leaves the base substrate the problem is mainly either due to some chemistry issue of ink (low resin or improper resin) or due to poor wettability of ink on the base substrate. However our ink supplier has given us a new concept today, according to them when adhesive is applied on the printed web (already coated with ink) during curing the adhesive is supposed to penetrate through the ink and reach the base substrate where it should make a bond with substrate or should reinforce the bond of ink with the base substrate. In case there is complete ink transfer it could be due to less coating of weight of adhesive which was not able to penetrated through the ink layer to reach the base film and thereby not increasing/reinforcing the bonding of ink with the base film. The ink system used is PVB based and the material combination is PET/Ink/Adhesive/PE.

We have also checked our records and have found that coating weight of adhesive is normal i.e. 2.6 gsm as per routine.

Please urgently comment if the underlined theory which is suggested by our ink supplier is true as per your experience as you also have good experience of inks could you also send us some technical reference articles to reinforce your point of view ?

Waiting for your urgent response.

Asim

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Blogmaster

Edward Cohen photo

Dr. Edward D. Cohen

Dr. Cohen is a technical consultant in all aspects of the web coating process. His expertise includes thin film coating and drying process development, coating application and drying of thin films, polyester base development, film defect mechanisms, formulating coatings, image analysis techniques for characterizing coating films and litigation support.

He has over 45 years experience in coating research and manufacturing technology with the DuPont Company and as a technical consultant to the converting and composites industries

He has extensive publications in the field and has co-authored several books: Modern Coating and Drying Technology, Coating and Drying and Defects: Troubleshooting Operating Problems, and chapters in Kirk-Othmer Encyclopedia of Chemical Technology and Water and Solvent Based Coating Technology. His honors are the John Tallmadge Award for Contributions to Coating technology, the AIMCAL President's award in recognition of Meritorious Service to AIMCAL and the Converting Industry, and the ISCST Founders Award. He was the founding president of the ISCST. He has a Bachelor of Science in Chemical Engineering from Tufts University and a Ph.D. in Physical Chemistry from the University of Delaware.