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Vacuum Web Coating

Blogmaster: Dr. Charles A. Bishop

19

The subject of pinholes can be contentious as it can depend on where you look and under what conditions you look as to how many and how big they appear. Pinholes can be produced by a number of different methods; coating debris that was present on the film surface that is later moved away leaving behind an uncoated area, pickoff of the coating where the coatings is not well adhered and is removed sometime later by hard contact with the back surface of the film whilst rolled up, prevention of coating adhesion by oligomer evaporating off the film surface or by spits from the evaporating source that prevent normal aluminium deposition. The oligomer vaporising or the spits may allow partial deposition and so may not be a pinhole with zero coating in the hole but may be a region of thinner aluminium deposition that shows a pronounced visible contrast when viewed in transmission.

I have seen many different ways of evaluating the level of pinholes. This includes simply holding the metalized film up and using the sky as the background illumination and the person holding the film then estimates the number of pinholes and decides if it is better or worse than normal. Obviously this is poor quality control and subject to large errors.

More typically a light box is used and a specific area of film is examined with the number of pinholes in the viewed area counted. This number is then recorded, compared and the quality of the coating judged against a reference number of pinholes per unit area.  Fewer than this number is good and more than this number is poor. Although this is a common method there can still be differences between measurements taken at different sites unless the design and construction of the light boxes is identical. 

The basic construction is for a box to contain a light with a flat top surface on which the metalized sample can be placed for evaluation. Where there can be differences are the light source, both in number, power and type of lamps. The lamps may have a white diffusing glass envelope and the box may have reflectors below or may just have all surfaces white. Above the lamps the top plate may be clear glass or a white diffuser material. The differences in lamps can change the light intensity as filament lamps are more of  appoint source of light whereas the fluorescent lamps already have a more diffuse output. The number and position of the lamps can also change the uniformity of the light across the top surface plate. The aim is to have as uniform illumination as possible over the whole surface rather than bright spots directly over each lamp.

If you get a film sample and increase the light intensity it is noticeable that there are fewer pinholes visible at low intensity that at a higher light intensity. Hence it is important to have identical light boxes if you want to be able to compare results. The higher intensity illumination makes it easier to see the finer pinholes and also the contrast differences where there are areas of reduced coating.

It is important to use a number of samples when assessing a roll of metalized film as the distribution of pinholes may be random although sometimes there are some differences that can be associated with other converting processes. Slitting is a dirty operation and even with vacuum extraction it can often be seen that there are more pinholes towards the slit edges that there are towards the centre of the film. Thus to get a full picture of the distribution of pinholes it may be necessary to compare several samples taken from the edges to another set taken from the centre of the web.

As many pinholes are derived from debris that is moved after the metallization it will also depend on how the film has been handled following metallization. The web will have been rewound in the vacuum system and then the samples taken either by cutting into the roll or by unwinding a length of material and cutting out the samples on a cutting table.  This may be more gentle handling than the film may see in other downstream converting. What can be done is to measure the sample for pinholes and then to brush the surface to evaluate if this produces more pinholes as more debris is moved. This can be revealing as to how much debris is on the film prior to metallization. This does add another variable as the type and pressure used when brushing can affect how much of the debris is moved around.  A lens brush used for cleaning camera optics is a very soft brush that if used in a single pass across the surface is probably as gentle as it is possible to get. However this may not be representative of the handling received in other converting processing. Using a second piece of film and dragging it across the surface may be a more representative and harsher treatment. I am sure there are many other options that people have used. Again it is important to be consistent from sample to sample and try to keep it independent of whoever does the test.

I hope this highlights why evaluating pinholes can be so difficult.

Posted in: Measurements

Comments

#455 mustafa homran
Friday, May 04, 2012 9:12 PM
how we can prevent or reduce pin hole in the film before metalizing or vacum coating in cpp cast film?
how we can reduce trim line in vacum coating ?
#457 Charles Bishop
Saturday, May 05, 2012 6:44 AM
It is always good to check what is on the surface of the film to see exactly what you are trying to improve. Once you have a measure of what the surface is like before you try to make improvements you can then measure again after each improvement and see which of the improvements you make has the most beneficial effect.

One way to evaluate the surface contamination is to use a test kit that is available from at least one of the tacky roll cleaning system suppliers (Teknek). This kit has a small hand roller with tacky roll material on it and you roll this down a length (say 1m or 5m) of film and then the roll is rolled for one revolution onto a high tack pad and all the debris collected by the roller is transferred onto the pad. This can then be looked at under a microscope and the number of particles for a given area counted. The distance you cleaned on the web and the circumference of the roll allows you to then calculate the number of particles per unit area on the web. The aim is to then make changes to reduce this number.

If you produce the CPP film then you can go back to the production line and evaluate where the debris might be coming from. This could be airborne and include human debris such as skin and hair fragments, mechanical debris from motors, fork lift trucks, paper, cores and may include contaminants from outside such as pollens. Controlling the atmosphere using filters will help but if too expensive to do the whole production hall then using strategically placed clean air hoods over exposed sections of the casting line would be an alternative strategy. The casting process may also produce debris in the form of monomer fumes that condense as a powder that can then accumulate and if disturbed will become airborne and reach the web. The web may become charged up due to triboelectric charging as it approaches and leaves each roller and this may be reduced by the use of more electrostatic neutralisers.
If the line includes slitting then evaluating the amount of debris produced during slitting over the lifetime of the slitting blades is likely to show up the increase in debris production as the blades become blunt. This may lead to replacing the blades more frequently. Using vacuum extract to not only remove the edge trim but also remove the debris is worth doing. If possible using extra vacuum extract coupled to electrostatic neutralisation helps to minimise this as a source of debris.

If you do not have access to the production line you are left with trying to clean the web up before it goes into the vacuum system. This can be done using either one of the tacky roll systems or by using the ultrasonic pulsed cleaned filtered electrostatically neutralised air jet with vacuum extract.

For all of these cleaning steps make sure that both sides of the web are considered as if the back surface is contaminated it will contaminate the front surface immediately the web is wound up into a roll.

Once the web has been cleaned it must not be re-contaminated and this means that betweent he cleaning process and re-winding the web must be protected by beign in a clean atmosphere with minimal electrostatic charge on the surface. Again this may be achieved by the use of a clean air hood and electrostatic neutralising system.
#458 Charles Bishop
Saturday, May 05, 2012 7:09 AM
The second question re. trim line in vacuum. Do you mean 'tram line' or 'railroad track' ? This is where when the web is held up to look at the coating in transmission there are a couple (or more) light and dark bands that run in the machine direction over long lengths of the roll.

If this is what you mean then this is as a result of the heat load in the deposition zone. The web heats up and wants to expand but the tension holds the web against the deposition drum. Once the temperature reaches a limit the transverse compression force becomes too much and the only way the web can relieve itself of this stress is to lif off the deposition drum. This allows the web to locally expand and so the coating deposited will cover the curved surface but as this curved surface (measured transversly to the machine direction) is longer than it would be if lying flat on the drum the coating is slightly thinner when on the curved web surface than when the coating deposits onto the web lying flat on the drum. As the eye con discriminate slight thickness variations it becomes quite easy to see in transmission later in the winding path.

There are three things that are done to minimise this problem. One is to use a spreader roll immediately before the web is laid onto the deposition drum. THis puts the web into tension transversely and so when the web heats up in the deposition zone the first expansion only reduces this spreader induced tension. Once the expansion has cancelled out this transverse tension any further heating will then put the web into transverse compression and once the web reaches the same temperature limit it will again result in tramlines. So when using a speader the heat load can be slightly higher than when a speader is not used.

The second thing that can be done is to simply increase the tension applied to the web around the deposition drum. This may be somewhat more risky as if the web reaches too high a temperature the yield strength will have fallen significantly and so an increase in tension may take the web beyond the yield strength and a permanent extension in the machine direction may result. It is not always easy to predict if this will occur as by increasing the tension not only is the web held more tightly onto the drum but this incresed pressure of the web onto the drum will increase the heat transfer coefficient and this will help reduce the web temperature.

The third option is to inject gas between the web and drum as the web makes contact with the drum. This gas is trapped and compressed between the web and drum and improves the heat transfer coefficient. Thsi improvement in heat transfer coefficient is often of the order of double or more and so the temperature is significantly reduced, more than simply by increasing the tension. This imporved heat transfer coefficient will reduce the web temperature and so reduce the transverse compression force and so reduce the propensity to wrinkle off the surface.

I only hope I have been answering the right question.

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Blogmaster

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Dr. Charles A. Bishop

Charles is a toolmaker by trade after completing a mechanical engineering apprenticeship. He then entered University and obtained a Bachelors degree in materials engineering with a Diploma in Industrial Studies. During his final year he first started work on vacuum based research, helping develop a process for manufacturing titanium based bone implants for tendon location. He went on to obtain a Masters degree and Doctorate following further research into vacuum deposition processes. During this time and as a postgraduate he also worked as a consultant.

Charles next spent time in industry working for various divisions of ICI including polyesters, nylon, Imagedata, Flex Products Inc., and explosives as well as contributing to other projects. In 1998 he took the opportunity to return to consultancy work and set up his own company.

Charles has more than 30 years experience in vacuum deposition mainly onto flexible webs. He has regularly contributed papers to conferences and recently has edited this blog on behalf of AIMCAL as well as being one of their presenters for various webinars and the more formal Converting School courses.

Charles has also published 2 books, Vacuum deposition onto webs, films and foils and Roll-to-roll vacuum deposition of barrier coatings.