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Blogmaster: Dr. Eldridge M. Mount III

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Question: We have a problem with 50micron BOPP film production.  We have observed an orange peel defect appears on both sides (Inside & Outside). This film will be metallized, so the smooth & clear appearance is a must, otherwise the defects will be clearly seen after metallization. Please comment, regarding orange peel problem, is there any relation with MFI of the copolymer? What is MFI of Copolymer & Homopolymer that we should use?

Answer:  Orange peel is a surface defect which is generally caused by a dirty casting roll.  So it would be generally seen on the chill roll surface but would be visible from both surfaces.   it creates a slightly irregular surface which then distorts the light passing through the film making it distorted.  And when examined closely has an appearance much like that of an orange peel surface hence the name.  If you have a rough film surface and then metallize it, the metal deposit will enhance the appearance of the defect when viewed through the film.  however, if you metallize the film surface opposite he orange peel and that surface is smooth you will not see the orange peel when viewing the metal surface directly, but if viewed from behind it will be visible.

If you are seeing variations in appearance with different resins of different melt flows (average viscosity level) then you are likely seeing a melt disturbance of the surface.  Because you have “orange peel” on both surfaces I assume you have a melt disturbance.  To have a melt disturbance free film you must have the skin layers a lower viscosity than the core.  Core viscosity is impacted by the core melt temperature, the MF of the virgin polymer and the percentage and MF of the reclaim added to the core.  Therefore you have to increase the MF of the skins or lower the MF of the core resin.  Typically you would want the skins to be 2MF units higher than the core, but this assumes good melt temperature levels and good quality reclaim resin.  You need to look at the viscosity of each layer to see how you need to choose your skin and core resins.  You also need to evaluate the screw performance to see what melt temperature you have for the core.  Once you know this you can engineer the coextrusion solution.

Posted in: Basics

Comments

Wednesday, November 02, 2011 7:47 AM
Dear Dr.Mount
I am producing BOPET film and some of our customers are complaining for ORANGE PEEL defect but we are unable to under stand that this defect can be in BOPET film also.
Please suggest possible causes and to rectify this defect.

With Regards
Siddhsuman Tiwari
Senior Manager Production
JBF RAK LLC
Ras Al Khaimah
UAE

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Blogmaster

Eldridge Mount photo Dr. Eldridge M. Mount III

Dr. Mount is an independent consultant in the coextrusion, extrusion, film, metallization and film converting industries. He is a leader in the development of metallized films for barrier applications and film laminations. His expertise is in oriented film product and process research, the design and implementation of extrusion systems and coextrusion die specification and system specification including installation and start-up. He is also recognized for trouble shooting mono and biaxial orientated film and sheet coextrusion, melt casting and melt pinning, and film surface treatment by corona, flame and plasma systems. EMMOUNT Technologies, LLC offers consulting and technical training in film orientation, barrier technologies, coextrusion and extrusion and measures polymer melt viscosity with a capillary rheometer.

Eldridge has over 30 years industrial experience in the extrusion and orientation of polypropylene and polyester films at ExxonMobil Chemical and ICI Americas Film Divisions. He managed the intellectual property of Mobil Chemical Films Division and has courtroom experience as an expert witness. A frequent contributor to SPE ANTEC, AIMCAL and TAPPI conferences, he is a member of the SPE Extrusion Division Board of Directors, and a Fellow and Honored Service Member of SPE. Appointed AIMCAL Metallizing Consultant in 2001 and a past VP of the Society of Plastics Engineers. He has a Bachelors degree in Chemistry from West Chester University and a ME and PhD in Chemical Engineering from Rensselear Polytechnic Institute.

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Eldridge M. Mount III

EMMOUNT Technologies, LLC

Beth M. Foederer

Optex Process Solutions, LLC